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A&R quiz chemistry(Day-5)

Update on: 18 Mar 2019, 11:09 AM

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ASSERTION : The Duma’s method is more applicable to nitrogen containing organic compounds than the Kjeldahl’s method. REASON : The Kjeldahl’s method does not give satisfactory results for compounds in which nitrogen is directly linked to oxygen.

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ASSERTION : Sodium ions are discharged in preference to hydrogen ions at a mercury cathode. REASON : The nature of cathode can affect the order of discharge of cations.

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ASSERTION : Be does not impart any characteristic colour to the bunsen flame. REASON : Due to its very high ionization energy, beryllium requires a large amount of energy for excitation of the electrons.

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ASSERTION : The O – O bond length in H2O2 is shorter than that of O2F2. REASON : H2O2 is an ionic compound.

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ASSERTION : Both, oxygen atom in O2 or O3 has an oxidation number of –2. REASON : Oxygen is assigned an oxidation number –2 in almost all their compounds.

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ASSERTION : Strength of oxyacids follow order : HIO4 < HBrO4 < HClO4. REASON : Acidic strength of oxyacids of same type formed by different elements depends on oxidation number.

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ASSERTION : Amongst the halogens, fluorine can oxidise the elements to the highest oxidation state. REASON : Due to small size of fluoride ion, it is difficult to oxidise fluoride ion to fluorine. Hence, reverse reaction takes place more easily.

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ASSERTION : Benzene on heating with conc. H2SO4 gives benzenesulphonic acid which when heated with superheated steam under pressure gives benzene. REASON : Sulphonation is a reversible process.

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ASSERTION : The number of tetrahedral voids is double the number of octahedral voids. REASON : The size of the tetrahedral voids is half of that of the octahedral void.

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ASSERTION : In a pressure cooker, the water is brought to boil. The cooker is then removed from the stove. Now, on removing the lid of pressure cooker, the water starts boiling again. REASON : The impurities in water bring down its boiling point.

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A&R quiz chemistry(Day-5)
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